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Mechanisms of stereocontrol for doubly silylene-bridged C-s- and C-1-symmetric zirconocene catalysts for propylene polymerization. Synthesis and molecular structure of Li-2[(1,2-Me2Si)(2){C5H2-4-(1R,2S,5R-menthyl)}{C5H-3,5-(CHMe2)(2)}].3THF and [(1,2-Me2Si)(2){eta(5)-C5H2-4-(1R,2S,5R-menthyl)}{eta(5)-C5H-3,5-(CHMe2)(2)}]ZrCl2
Authors: Veghini, D Henling, LM Burkhardt, TJ Bercaw, JE
Citation: D. Veghini et al., Mechanisms of stereocontrol for doubly silylene-bridged C-s- and C-1-symmetric zirconocene catalysts for propylene polymerization. Synthesis and molecular structure of Li-2[(1,2-Me2Si)(2){C5H2-4-(1R,2S,5R-menthyl)}{C5H-3,5-(CHMe2)(2)}].3THF and [(1,2-Me2Si)(2){eta(5)-C5H2-4-(1R,2S,5R-menthyl)}{eta(5)-C5H-3,5-(CHMe2)(2)}]ZrCl2, J AM CHEM S, 121(3), 1999, pp. 564-573
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