INTRAMOLECULAR DIELS-ALDER REACTIONS OF THIO-SUBSTITUTED DIENES WITH ENONES

Authors
CHOU SSP YU YJ
Citation
Ssp. Chou et Yj. Yu, INTRAMOLECULAR DIELS-ALDER REACTIONS OF THIO-SUBSTITUTED DIENES WITH ENONES, Journal of the Chinese Chemical Society, 44(4), 1997, pp. 373-378
Citations number
30
Categorie Soggetti
Chemistry
Journal title
Journal of the Chinese Chemical Society → ACNP
ISSN journal
00094536
Volume
44
Issue
4
Year of publication
1997
Pages
373 - 378
Database
ISI
SICI code
0009-4536(1997)44:4<373:IDROTD>2.0.ZU;2-A
Abstract
Thio-substituted dienes bearing an enone moiety were readily prepared from 3-sulfolenes, and their intramolecular Diels-Alder (IMDA) reactio ns were studied. Octahydronaphthalenones were produced in good yield w ith high stereoselectivity. Hexahydroindenones were also obtained, but the stereoselectivity was lower.