ACETYLENIC PHOSPHINES BRIDGING 2 CLUSTER UNITS - MOLECULAR-STRUCTURE OF (RU-3(MU-H)(MU(3)-C2BUT)(CO)(8))(2)(MU-DPPA) [DPPA = C-2(PPH2)(2)]

Authors
BRUCE MI HUMPHREY PA SKELTON BW WHITE AH
Citation
Mi. Bruce et al., ACETYLENIC PHOSPHINES BRIDGING 2 CLUSTER UNITS - MOLECULAR-STRUCTURE OF (RU-3(MU-H)(MU(3)-C2BUT)(CO)(8))(2)(MU-DPPA) [DPPA = C-2(PPH2)(2)], Australian Journal of Chemistry, 50(6), 1997, pp. 535-538
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Australian Journal of Chemistry → ACNP
ISSN journal
00049425
Volume
50
Issue
6
Year of publication
1997
Pages
535 - 538
Database
ISI
SICI code
0004-9425(1997)50:6<535:APB2CU>2.0.ZU;2-5
Abstract
The syntheses of two complexes consisting of two Ru-3(mu-H)(mu(3)-C2Bu t)(CO)(8) clusters bridged by acetylenic ditertiary phosphines, C-2(PR 2)(2) [R = Ph (3), Bu-n (4)], are described. The molecular structure o f (3) confirms that substitution of the cluster at the ruthenium which is a bonded to the acetylide has occurred. The structural parameters closely resemble those of Ru-3(mu-H)(mu(3)-C2But)(CO)(8)(L) [L = CO, P Ph2(OEt)].