PREPARATION OF BIS(TRIFLUOROMETHYL) COMPOUNDS VIA FUNCTIONALIZATION OF 1,1,1,3,3,5,5,5-OCTAFLUOROPENTANE

Authors
VANDERPUY M
Citation
M. Vanderpuy, PREPARATION OF BIS(TRIFLUOROMETHYL) COMPOUNDS VIA FUNCTIONALIZATION OF 1,1,1,3,3,5,5,5-OCTAFLUOROPENTANE, Journal of organic chemistry, 62(19), 1997, pp. 6466-6468
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
62
Issue
19
Year of publication
1997
Pages
6466 - 6468
Database
ISI
SICI code
0022-3263(1997)62:19<6466:POBCVF>2.0.ZU;2-L
Abstract
The hydrochlorofluorocarbon CF3CH2CCl2CH2CF3 (3) was prepared from the hydrofluorocarbon CF3CH2CF2CH2CF3, by a selective Cl-F exchange react ion using AlCl3. Compound 3 was derivatized further to provide novel f luorinated intermediates including CF3CH=C=CHCF3, CF3CH2C(O)CH2CF3, an d CF3CH2CH(OH)CH2CF3.