Ap. Tyutnev et al., THEORETICAL-ANALYSIS OF TRANSIENT RADIATION-INDUCED CONDUCTIVITY OF POLYMERS WITHIN THE ROSE-FOWLER-VAISBERG MODEL, CHEMICAL PHYSICS REPORTS, 16(2), 1997, pp. 277-300
The transient behavior of radiation-induced conductivity both during i
rradiation and at the relaxation stage after cessation of irradiation
is studied. An analytical expression describing the decay of radiation
-induced electric conductivity is derived within the Rose-Fowler-Vaisb
erg (RFV) model at low intensities of the radiation pulses is suggeste
d and compared with direct numerical computations. Convenient experime
ntal techniques for determining the basic parameters of the RFV model
(effective frequency factor, displacement of thermalized charge carrie
rs prior to their capture in unit electric field, and dispersive param
eter) are proposed based on the calculation results. The suggested met
hod for determining parameters of the RFV model is checked using as an
example the available literary data for polystyrene and low-density p
olyethylene. Along with an analysis of the low-signal mode, we scrutin
ized also nonlinear effects associated with bimolecular recombination
of charge carriers and filling the traps. The temperature dependence o
f the radiation-induced conductivity and its relation to molecular mob
ility in polymers were tentatively studied.