The zeta potential of different lithotypes of two coals with high cont
ent of inertinite in Shenfu Coalfield has been studied. Moreover, the
effects of pH value and the addition of surfactants and inorganic salt
s on zeta potential have also been discussed. It has been concluded th
at the zero potential point (ZPP) of vitrain is between about 3.30 and
3.40 of pH value, but that of fusain is between 2.00 and 2.10 of pH v
alue. Furthermore, it has been found that vitrain could reach its ZPP
once a small amount of cationic surfactants and some inorganic salts w
ere added to pulps. However, only when a large amount of cationic surf
actants and some inorganic salts were added to pulps, could fusain rea
ch its ZPP. The conclusions are useful in the efficient separation and
preparation of single petrographic constituent.