MATHEMATICAL-MODEL OF THE INHIBITION EFFECT OF 2,4,6-TRI-TERT-BUTYLPHENOL IN LOW-DENSITY POLY(ETHYLENE) MELT

Authors
KHARITONOV VV PSIKHA BL ZAIKOV GE
Citation
Vv. Kharitonov et al., MATHEMATICAL-MODEL OF THE INHIBITION EFFECT OF 2,4,6-TRI-TERT-BUTYLPHENOL IN LOW-DENSITY POLY(ETHYLENE) MELT, CHEMICAL PHYSICS REPORTS, 16(3), 1997, pp. 419-429
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
CHEMICAL PHYSICS REPORTS → ACNP
ISSN journal
10741550
Volume
16
Issue
3
Year of publication
1997
Pages
419 - 429
Database
ISI
SICI code
1074-1550(1997)16:3<419:MOTIEO>2.0.ZU;2-6
Abstract
The inhibition effect of antioxidant 2,4,6-tri-tert-butylphenol on oxi dation of low-density melt of poly(ethylene) is studied at 120, 130, a nd 140 degrees C. The rate-controlling reactions of the inhibition mec hanism and their kinetic parameters are determined at each of the cove red temperatures. Variation of tri-tert-butylphenol efficiency with in creasing temperature is analyzed.