Q. Tan et D. Viehland, GRAIN-SIZE DEPENDENCE OF RELAXOR CHARACTERISTICS IN LA-MODIFIED LEAD-ZIRCONATE-TITANATE, Ferroelectrics, 193(1-4), 1997, pp. 157-165
Studies have been performed on a series of La-modified lead zirconate
titanate (PLZT) specimens with grain sizes between 0.6 and 6 mu m by d
ielectric spectroscopy and transmission electron microscopy. These inv
estigations have revealed an increase in the degree of relaxer charact
eristics with decreasing grain size for tetragonal-structured PLZT. In
addition, small grain sizes were found to favor tweed-like structures
and polar nanodomains, over normal micron-sized ferroelectric domains
.