K. Yoshino et al., STATIC AND DYNAMIC PROPERTIES OF FERROELECTRIC LIQUID-CRYSTAL AND THEIR NOVEL APPLICATIONS, Ferroelectrics, 197(1-4), 1997, pp. 637-645
The properties of ferroelectric and polymeric ferroelectric liquid cry
stals (FLC and PFLC) have been studied as functions of molecular struc
ture, bias voltage and boundary conditions. Anomalous rotation of the
smectic layer has been observed in the ferroelectric and antiferroelec
tric phases. The direction of the rotation is reversible with the pola
rity reversal of the applied voltage. The transition temperature (Tc)
from smectic A to smectic C becomes higher with decreasing thickness
in free-standing FLC films. On the other hand, Tc in the free-standing
PFLC film is similar to that of thick sandwich cell. Electro-optic ef
fects in FLC and PFLC in spin-coated films, free-standing films and in
sandwich cells have also been clarified.