THERMAL-EXPLOSION IN A VIBRATIONALLY NONEQUILIBRIUM GAS

Citation
Ev. Kulaga et al., THERMAL-EXPLOSION IN A VIBRATIONALLY NONEQUILIBRIUM GAS, CHEMICAL PHYSICS REPORTS, 16(5), 1997, pp. 759-772
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
10741550
Volume
16
Issue
5
Year of publication
1997
Pages
759 - 772
Database
ISI
SICI code
1074-1550(1997)16:5<759:TIAVNG>2.0.ZU;2-W
Abstract
The problem on thermal explosion in a nonequilibrium gas sustained in a nonequilibrium state by pumping energy into vibrational degrees of f reedom of the gas molecules and removing heat through the gas interfac e with the ambient medium, is solved under auxiliary constraints impos ed either on the state of the vibrational manifold or on the pumping r ate. The results of numerical solution of the equation of energy conse rvation are compared with the solution of a similar problem, obtained by the Frank-Kamenetskii algorithm. The values of the parameters, at w hich the system becomes thermally unstable, are determined. Prediction s of the thermal explosion theory are correlated with calculations by the method of evolution of small hydrodynamic perturbations.