A polar glass-ceramic with crystallites Sr2TiSi2O8 and SrTiO3 is prepa
red. The dielectric and pyroelectric properties are studied in the tem
perature range from 10 to 300K. The pyroelectric coefficient is negati
ve above 40K and becomes positive below this temperature. The sign-cha
nge of pyroelectric coefficient is ascribed to the structural phase tr
ansition of SrTiO3.