Tetragonal-tungsten-bronze-type Ba5Li2Ti2Nb8O30 ceramics have been den
sified. Such materials are both ferroelectric and ionic conductor. A m
aximum of epsilon'(r), appears at T-c approximate to 580K. Another sma
ll peak has been found at about 305K, it probably results from a cryst
allographic transition. In addition, a very strong frequency dispersio
n, related to the ionic conduction, occurs at T greater than or equal
to Tc.