A new model for diphasic composite changing its connectivity from 3-0
to 0-3 via 3-3 are proposed here, which combined 3-0 (0-3) and 3-3 mod
els. Dielectric constant of the composite and dielectric, elastic and
piezoelectric constants of porous PZT ceramics are derived as a functi
on of volume fraction of phase 1 and porosity based on the model, resp
ectively. These results were compared with previous obtained experimen
tal data on Pb(Mg-1/3 Nb-2/3)O-3-pyrochlore phase mixture and highly p
orous PZT ceramics. Assuming that the diphasic composite changes its c
onnectivity from 3-0 to 0-3 via 3-3, a good agreement between experime
ntal and theoretical results is observed.