The accuracy of and detection limits for trace element analysis using
the electron and proton microprobes have been compared using glass sam
ples prepared from whole rock standard powders BE-N basalt, AC-E grani
te and W-2 diabase. The capabilities and advantages and disadvantages
of both techniques for trace element analysis have been examined. The
effect of varying the kV on the detection limits in electron microprob
e analysis is examined for a number of standard reference samples for
both high and low energy lines. (C) 1997 Elsevier Science Ltd.