SYNTHESIS OF BIS(2,6-DIMESITYL-4-METHYLPHENYL)PHOSPHAARSENE AND EPR OF ITS RADICAL-ANION

Authors
TSUJI K FUJII Y SASAKI S YOSHIFUJI M
Citation
K. Tsuji et al., SYNTHESIS OF BIS(2,6-DIMESITYL-4-METHYLPHENYL)PHOSPHAARSENE AND EPR OF ITS RADICAL-ANION, Chemistry Letters, (9), 1997, pp. 855-856
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1997
Pages
855 - 856
Database
ISI
SICI code
0366-7022(1997):9<855:SOBAEO>2.0.ZU;2-E
Abstract
Novel bis(2,6-dimesityl-4-methylphenyl)phosphaarsene was synthesized b y the coupling reaction of 2,6-dimesityl-4-methylphenylphosphine with dichloro(2,6-dimesityl-4-methylphenyl)arsine in the presence of 1,8-di azabicyclo[5.4.0]undec-7-ene and isolated as stable crystals. The radi cal anion generated by the sodium metal reduction of the phosphaarsene was investigated by X-band EPR.