SYNTHESIS OF MICROPOROUS ALUMINUM METHYLPHOSPHONATE ALMEPO-ALPHA BY STEAM-INDUCED TOPOTACTIC TRANSFORMATION OF ALMEPO-BETA

Authors
MAEDA K SASAKI A WATANABE K KIYOZUMI Y MIZUKAMI F
Citation
K. Maeda et al., SYNTHESIS OF MICROPOROUS ALUMINUM METHYLPHOSPHONATE ALMEPO-ALPHA BY STEAM-INDUCED TOPOTACTIC TRANSFORMATION OF ALMEPO-BETA, Chemistry Letters, (9), 1997, pp. 879-880
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1997
Pages
879 - 880
Database
ISI
SICI code
0366-7022(1997):9<879:SOMAMA>2.0.ZU;2-R
Abstract
Steaming treatment of AlMepO-beta at 500 degrees C induces transformat ion into AlMepO-alpha. This procedure easily gives pure AlMepO-alpha w ith a large adsorption capacity. A topotactic transformation mechanism through coordination of water molecules at an aluminum site is propos ed from comparison of both the framework structures.