SYNTHESIS AND STRUCTURE OF A TRINUCLEAR RHENIUM CLUSTER COMPLEX [PET3H][RE-3(MU(3)-S)(MU-S)(3)CL-6(PET3)(3)]

Authors
MIYAKE N IMOTO H SAITO T
Citation
N. Miyake et al., SYNTHESIS AND STRUCTURE OF A TRINUCLEAR RHENIUM CLUSTER COMPLEX [PET3H][RE-3(MU(3)-S)(MU-S)(3)CL-6(PET3)(3)], Chemistry Letters, (9), 1997, pp. 913-914
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1997
Pages
913 - 914
Database
ISI
SICI code
0366-7022(1997):9<913:SASOAT>2.0.ZU;2-#
Abstract
Reaction of [Re-3(mu(3)-S)mu-S-2)(3)Cl-6]Cl with triethylphosphine in benzene formed [PEt3H][Re-3(mu(3)-S)mu-S)(3)Cl-6(PEt3)(3)]. The triang ular cluster has eight metal cluster electrons and the cluster core re sembles that of [Mo-3(mu(3)-S)(mu-S)(3)Cl4L5] cluster complexes.