SYNTHESIS, STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF NEW UNSYMMETRICAL METAL DITHIOLATE COMPLEXES

Authors
KATO R KASHIMURA Y SAWA H OKANO Y
Citation
R. Kato et al., SYNTHESIS, STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF NEW UNSYMMETRICAL METAL DITHIOLATE COMPLEXES, Chemistry Letters, (9), 1997, pp. 921-922
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1997
Pages
921 - 922
Database
ISI
SICI code
0366-7022(1997):9<921:SSAEPO>2.0.ZU;2-T
Abstract
New ''unsymmetrical'' (mixed ligand) metal dithiolate complexes, expec ted as components of molecular conductors, have been obtained by a lig and-exchange reaction in refluxing acetone, followed by isolation with a preparative HPLC (ODP; acetonitrile-H2O). Their electrochemical dat a suggest that the acceptor (donor) ability and the on-site Coulomb en ergy for the ''unsymmetrical'' complexes can be tuned by a combination of ligands.