REMOVAL OF ORGANIC SULFUR IN COAL BY THE USE OF ANHYDROUS HF AND SUPERACID HF BF3/

Citation
K. Shimizu et al., REMOVAL OF ORGANIC SULFUR IN COAL BY THE USE OF ANHYDROUS HF AND SUPERACID HF BF3/, Chemistry Letters, (9), 1997, pp. 943-944
Citations number
5
Categorie Soggetti
Chemistry
Journal title
ISSN journal
03667022
Issue
9
Year of publication
1997
Pages
943 - 944
Database
ISI
SICI code
0366-7022(1997):9<943:ROOSIC>2.0.ZU;2-L
Abstract
Anhydrous hydrogen fluoride (HF) and HF combined with a small amount o f boron trifluoride(BF3) desulphurized high-sulphur coal in the presen ce of hydrocarbons without H-2 in mild reaction conditions. HF removed mainly sulphidic and oxidized sulphur. HF/BF3 decreased thiophenic su lphur as well as sulphidic and oxidized sulphur although the extent of desulphurization was almost the same as that with HF alone.