Anhydrous hydrogen fluoride (HF) and HF combined with a small amount o
f boron trifluoride(BF3) desulphurized high-sulphur coal in the presen
ce of hydrocarbons without H-2 in mild reaction conditions. HF removed
mainly sulphidic and oxidized sulphur. HF/BF3 decreased thiophenic su
lphur as well as sulphidic and oxidized sulphur although the extent of
desulphurization was almost the same as that with HF alone.