CHIRAL BIS(OXAZOLINYL)PHENYL RHODIUM AND PALLADIUM COMPLEXES

Authors
MOTOYAMA Y MAKIHARA N MIKAMI Y AOKI K NISHIYAMA H
Citation
Y. Motoyama et al., CHIRAL BIS(OXAZOLINYL)PHENYL RHODIUM AND PALLADIUM COMPLEXES, Chemistry Letters, (9), 1997, pp. 951-952
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
9
Year of publication
1997
Pages
951 - 952
Database
ISI
SICI code
0366-7022(1997):9<951:CBRAPC>2.0.ZU;2-7
Abstract
The transmetalation of Phebox-ip-SnMe3 [Phebox = 2,6-bis(oxazolinyl)ph enyl] 1c with RhCl3(H2O)(3) and PdCl2(PhCN)(2) gave (Phebox-ip)RhCl2(H 2O) 2a and (Phebox-ip)PdCl 3 under mild conditions in 45% and 96% yiel ds, respectively. The crystal structures of (Phebox-ip)Rh Cl-2(t-BuNC) 2b, which was obtained by the reaction of 2a with t-BuNC, and 3 have bees determined by X-ray diffraction.