STRUCTURE OF CHLOROHYDROXONITROSYL(TERPYRIDINE)RUTHENIUM(II) HEXAFLUOROPHOSPHATE

Authors
BRYAN CD BRYAN TA CORDES AW DURHAM B JETER DY YARBROUGH JC
Citation
Cd. Bryan et al., STRUCTURE OF CHLOROHYDROXONITROSYL(TERPYRIDINE)RUTHENIUM(II) HEXAFLUOROPHOSPHATE, Journal of chemical crystallography, 27(7), 1997, pp. 413-415
Citations number
13
Categorie Soggetti
Crystallography,Spectroscopy
Journal title
Journal of chemical crystallography → ACNP
ISSN journal
10741542
Volume
27
Issue
7
Year of publication
1997
Pages
413 - 415
Database
ISI
SICI code
1074-1542(1997)27:7<413:SOCH>2.0.ZU;2-V
Abstract
The title complex has the NO group trans to the hydroxyl ligand and th e chloride ion in the plane of the tripyridyl ligand. The Ru-O and Ru- N(O) distances are 1.939(5) Angstrom and 1.764(6) Angstrom, respective ly; the Ru-N-O bond angle is 171.7(6)degrees. These values are consist ent with previously reported shortening of Ru-O distances when trans t o a Linear NO ligand. The space group of the structure is P2(1)/c, wit h a = 9.7213(9) Angstrom, b = 13.9318(11) Angstrom, c = 14.523(4) Angs trom, and beta = 105.820(13)degrees.