IMPEDANCE MEASUREMENTS ON CEMENT PASTE

The present paper is devoted to the study of the high frequency region of the impedance spectrum, and focused at determining the origin of t he time constants in the impedance and their relation to the dielectri c properties of cement paste. The origin of the intermediate frequency capacitive range was investigated by intercalating polyester sheets b etween the paste sample and the graphite electrodes. It was concluded that the dielectric constant of cement paste can be determined only wh en impedance measurements are performed to frequencies higher than 10 MHz. Oven dried cement paste presents a single almost perfect capaciti ve behaviour with a dielectric constant, epsilon, below 10. In partial ly moistened cement paste the higher frequency range gives a reasonabl e epsilon (approximate to 80) for a water containing material. It is c oncluded that the interpretation of the high values of epsilon in term s of the DAF effect does not seem correct. (C) 1997 Elsevier Science L td.