A STUDY OF THE INTRAMOLECULAR STILLE CROSS-COUPLING REACTION OF VINYLSTANNYL CHLOROFORMATES - APPLICATION TO THE SYNTHESIS OF ALPHA-METHYLENE LACTONES

Authors
ADLINGTON RM BALDWIN JE GANSAUER A MCCOULL W RUSSELL AT
Citation
Rm. Adlington et al., A STUDY OF THE INTRAMOLECULAR STILLE CROSS-COUPLING REACTION OF VINYLSTANNYL CHLOROFORMATES - APPLICATION TO THE SYNTHESIS OF ALPHA-METHYLENE LACTONES, Journal of the Chemical Society. Perkin transactions. I, (13), 1994, pp. 1697-1701
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
13
Year of publication
1994
Pages
1697 - 1701
Database
ISI
SICI code
0300-922X(1994):13<1697:ASOTIS>2.0.ZU;2-L
Abstract
An intramolecular Stille cross coupling of vinylstannyl chloroformates catalysed by trans-benzylchlorobis(triphenylphosphine) palladium(II) has been investigated and shown to be useful for the preparation of al pha-methylene lactones. A novel method for the chloroformylation of al cohols in the presence of vinylstannanes is also described.