EPR OF GRAPHITE AND FULLERENES

Authors
STANKOWSKI J PIEKARASADY L KEMPINSKI W HUMINIECKI O SCZANIECKI PB
Citation
J. Stankowski et al., EPR OF GRAPHITE AND FULLERENES, Fullerene science and technology, 5(6), 1997, pp. 1203-1217
Citations number
28
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical","Material Science
Journal title
Fullerene science and technology → ACNP
ISSN journal
1064122X
Volume
5
Issue
6
Year of publication
1997
Pages
1203 - 1217
Database
ISI
SICI code
1064-122X(1997)5:6<1203:EOGAF>2.0.ZU;2-N
Abstract
Analysis of the EPR results for graphite and fullerenes has led to the development of a model for the g-factor in fullerene based on the ana logy between graphite and fullerene, Pressure dependence of g-factor i n C-60 powder confirms the validity of this model, C-13 hyperfine spli tting of 0.36 mT in pristine fullerene is also reported. The g-factors of C-60(-1) and C-60(-3) in a solution and in a different KxC60 fulle rides are presented. C-60(+n) states should be described by the spectr oscopic splitting factor larger than that of a free spin.