MOLECULAR-COMPLEXES OF EXPLOSIVES WITH CYCLODEXTRINS .2. PREPARATION AND CHARACTERIZATION OF A SOLID COMPLEX OF BETA-CYCLODEXTRIN WITH THE NITRAMINE 1,3,3-TRINITROAZETIDINE (TNAZ)

Authors
CAHILL S RINZLER AG OWENS FJ BULUSU S
Citation
S. Cahill et al., MOLECULAR-COMPLEXES OF EXPLOSIVES WITH CYCLODEXTRINS .2. PREPARATION AND CHARACTERIZATION OF A SOLID COMPLEX OF BETA-CYCLODEXTRIN WITH THE NITRAMINE 1,3,3-TRINITROAZETIDINE (TNAZ), Journal of physical chemistry, 98(28), 1994, pp. 7095-7100
Citations number
11
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
98
Issue
28
Year of publication
1994
Pages
7095 - 7100
Database
ISI
SICI code
0022-3654(1994)98:28<7095:MOEWC.>2.0.ZU;2-F
Abstract
A solid complex between 1,3,3-trinitroazetidine (TNAZ) and beta-cyclod extrin has been isolated for the first time and characterized by the a pplication of solution and solid-state NMR techniques, Raman spectrosc opy, and differential scanning calorimetry experiments. All the techni ques show clear differences in properties of the solid product from th ose of a simple physical mixture of the components, and when taken tog ether, they provide convincing evidence for the complex formation.