DISSOCIATIVE PHOTOIONIZATION OF MO(CO)(6) IN THE PHOTON ENERGY-RANGE OF 8-40 EV

Authors
QI F YANG SH SHENG LS YE WQ GAO H ZHANG YW YU SQ
Citation
F. Qi et al., DISSOCIATIVE PHOTOIONIZATION OF MO(CO)(6) IN THE PHOTON ENERGY-RANGE OF 8-40 EV, The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 101(39), 1997, pp. 7194-7199
Citations number
31
Categorie Soggetti
Chemistry Physical
Journal title
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory → ACNP
ISSN journal
10895639
Volume
101
Issue
39
Year of publication
1997
Pages
7194 - 7199
Database
ISI
SICI code
1089-5639(1997)101:39<7194:DPOMIT>2.0.ZU;2-6
Abstract
Twelve ions have been observed in the dissociative photoionization stu dies of Mo(CO)(6) using a synchrotron radiation source in the photon e nergy range of 8-40 eV. The photoionization efficiency (PIE) curves of these ions from the dissociative ionization of Mo(CO)(6) have been me asured for the first time. Appearance potentials (AP) of all the ions have been determined from their PIE curves and these AP values, in tur n, bring about a series of bond dissociation energy (BDE) data for the intermediate ions produced by photoionization/fragmentation.