INDUCED DECOMPOSITION OF DI(TERT-BUTYL)TRIOXIDE

Authors
KHURSAN SL KHALIZOV AF SHERESHOVETS VV
Citation
Sl. Khursan et al., INDUCED DECOMPOSITION OF DI(TERT-BUTYL)TRIOXIDE, Russian chemical bulletin, 46(5), 1997, pp. 884-887
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
5
Year of publication
1997
Pages
884 - 887
Database
ISI
SICI code
1066-5285(1997)46:5<884:IDOD>2.0.ZU;2-G
Abstract
Thermal decomposition of di(tert-butyl)trioxide ((BuOOOBut)-O-t) in a wide range of concentrations was studied by visible and IR chemilumine scence. Induced decomposition of (BuOOOBut)-O-t caused by its reaction with the peroxy radicals formed in the solvent (CH2Cl2) was found and investigated.