SYNTHESIS AND CHARACTERISTICS OF NOVEL PENTANUCLEAR COMPLEXES CO)(2)(ETA(1),ETA(5)-C5H4CO2)](2)M(ETA(5)-C5H5)(2) (M = TI, ZR)

Authors
ORLOVA TY NEKRASOV YS PETROVSKII PV EZERNITSKAYA MG LOKSHIN BV MINACHEVA MK STRUNKINA LA LEPENDINA OL MAGDESIEVA TV MILOVANOV SV BUTIN KP
Citation
Ty. Orlova et al., SYNTHESIS AND CHARACTERISTICS OF NOVEL PENTANUCLEAR COMPLEXES CO)(2)(ETA(1),ETA(5)-C5H4CO2)](2)M(ETA(5)-C5H5)(2) (M = TI, ZR), Russian chemical bulletin, 46(5), 1997, pp. 1018-1021
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
5
Year of publication
1997
Pages
1018 - 1021
Database
ISI
SICI code
1066-5285(1997)46:5<1018:SACONP>2.0.ZU;2-Z
Abstract
The reaction of Cp2MCl2 complexes (M = Ti and Zr) with 2 equiv. of (3) Mn(eta(1),eta(5)-C5H4)Fe(CO)2(eta(5)-C5H4COONa) results in the formati on of the pentanuclear complexes )2(eta(1),eta(5)-C5H4CO2)](2)M(eta(5) -(CH5)-H-5)2, which are characterized by IR and H-1 NMR spectroscopy a nd cyclic voltammetry.