HOMOGENEOUS MODELING OF AMMOXIDATION CHEMISTRY - NITRILE FORMATION USING A SOLUBLE ANALOG OF MOO3

Authors
MOHS TR DU YH PLASHKO B MAATTA EA
Citation
Tr. Mohs et al., HOMOGENEOUS MODELING OF AMMOXIDATION CHEMISTRY - NITRILE FORMATION USING A SOLUBLE ANALOG OF MOO3, Chemical communications, (18), 1997, pp. 1707-1708
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1997
Pages
1707 - 1708
Database
ISI
SICI code
1359-7345(1997):18<1707:HMOAC->2.0.ZU;2-U
Abstract
The reaction of the soluble MoO3 analogue [Mo6O19](2-) with Ph3P=NCH2P h replicates key features of heterogeneous ammoxidation chemistry by p roducing moderate yields of PhC=N through the proposed intermediacy of the benzylimido hexamolybdate complex [Mo6O18(NCH2Ph)](2-).