A. Muller et al., [(MO-VI(8)V-IV(4)O-36(V-VO4)(V-IVO)(2))(N)](7N-) - CAPPED ALPHA-KEGGIN FRAGMENTS LINKED TO A CHAIN, Chemical communications, (18), 1997, pp. 1715-1716
The synthesis and single-crystal X-ray structure analysis of the unusu
al Mo/V polyoxometalate compound K6.5[Mo(VI)8V(IV)4(O)36((VO4)-O-V)((V
O)-O-IV)(2)]. 12.5H(2)O which contains capped alpha-Keggin fragments l
inked to a chain is reported; this chain is an interesting object for
magnetochemists and can be considered to consist of an assembly of ele
ctron storage units.