I. Hamachi et al., PHOTOCONTROL OF THE REDOX STATE OF RUTHENIUM-TRIS(BIPYRIDINE)-APPENDED CYTOCHROME B(562), Chemical communications, (18), 1997, pp. 1735-1736
Ruthenium-tris(bipyridine)-appended heme is successfully reconstituted
with apo-cytochrome b(562) (Cyt-b(562)); the redox state of the activ
e site in the resultant semisynthetic Cyt-b(562) can be switched by vi
sible light irradiation.