REMARKABLE EDGE LIGATION OF A TRIPHOSPHACYCLOPENTENYL RING-SYSTEM - SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURE OF I(ETA(5)-P3C2BU2T)(ETA(2)-P3C2BU2TCH(SIME3)(2)ME)]

Authors
CALIMAN V HITCHCOCK PB NIXON JF
Citation
V. Caliman et al., REMARKABLE EDGE LIGATION OF A TRIPHOSPHACYCLOPENTENYL RING-SYSTEM - SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURE OF I(ETA(5)-P3C2BU2T)(ETA(2)-P3C2BU2TCH(SIME3)(2)ME)], Chemical communications, (18), 1997, pp. 1739-1740
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1997
Pages
1739 - 1740
Database
ISI
SICI code
1359-7345(1997):18<1739:RELOAT>2.0.ZU;2-H
Abstract
In the nickel(II) complex 5)-P3C2Bu2t)(eta(2)-(P3C2Bu2CH)-C-t-(SiMe3)( 2)Me}] the triphosphacyclopentenyl ring (P3C2BU2CH)-C-t(SiMe3)(2)Me is unexpectedly coordinated to the metal exclusively via the two adjacen t saturated ring phosphorus atoms, rather than via the 2-phosphaallyl fragment.