FIRST TETRATHIOLATE-BRIDGED DINUCLEAR MOLYBDACARBABORANES - SCISSION AND FORMATION OF THE C-C CLUSTER BOND DURING OXIDATION PROCESSES

Authors
KIM JH LAMRANI M HWANG JW DO Y
Citation
Jh. Kim et al., FIRST TETRATHIOLATE-BRIDGED DINUCLEAR MOLYBDACARBABORANES - SCISSION AND FORMATION OF THE C-C CLUSTER BOND DURING OXIDATION PROCESSES, Chemical communications, (18), 1997, pp. 1761-1762
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1997
Pages
1761 - 1762
Database
ISI
SICI code
1359-7345(1997):18<1761:FTDM-S>2.0.ZU;2-B
Abstract
Unprecedented tetrathiolate-bridged dinuclear ionic molybdacarbaborane s [(C2B9H11)Mo(SPh)(2)](2)(n-) (n = 2, 1) are prepared by successive o xidation of [(C2B9H11)Mo-II-(CO)(2)(SPh)(2)](2-) with diphenyl disulfi de and iodosylbenzene: X-ray crystal structure determinations and NMR studies show unusual scission and reformation of the C-C carbaborane c age bond.