LUMINESCENT GOLD(I) SUPERMOLECULES WITH TRITHIOCYANURIC ACID - CRYSTAL-STRUCTURE, SPECTROSCOPIC AND PHOTOPHYSICAL PROPERTIES

Citation
Bc. Tzeng et al., LUMINESCENT GOLD(I) SUPERMOLECULES WITH TRITHIOCYANURIC ACID - CRYSTAL-STRUCTURE, SPECTROSCOPIC AND PHOTOPHYSICAL PROPERTIES, Chemical communications, (18), 1997, pp. 1771-1772
Citations number
19
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
18
Year of publication
1997
Pages
1771 - 1772
Database
ISI
SICI code
1359-7345(1997):18<1771:LGSWTA>2.0.ZU;2-K
Abstract
The first example of an ordered array of Au-6 clusters with trithiocya nuric acid, [(LAu)(AuPPhMe2)(2)](2) (H3L = trithiocyanuric acid), is p repared and characterized by X-ray crystallography; it has a two-dimen sional structure via intermolecular Au-I ... Au-I interactions and pos sesses photoluminescence properties; the ability of trithiocyanuric ac id to act as a bridging ligand for molecular assembly of two-dimension al polymeric solids is demonstrated.