CATALYTIC ASYMMETRIC CYCLOPROPANATION OF ELECTRON-DEFICIENT ALKENES MEDIATED BY CHIRAL SULFIDES

Authors
AGGARWAL VK SMITH HW JONES RVH FIELDHOUSE R
Citation
Vk. Aggarwal et al., CATALYTIC ASYMMETRIC CYCLOPROPANATION OF ELECTRON-DEFICIENT ALKENES MEDIATED BY CHIRAL SULFIDES, Chemical communications, (18), 1997, pp. 1785-1786
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1997
Pages
1785 - 1786
Database
ISI
SICI code
1359-7345(1997):18<1785:CACOEA>2.0.ZU;2-L
Abstract
Catalytic asymmetric cylopropanation of enones has been achieved using diazo compounds, catalytic quantities of a metal catalyst and a camph or-derived thioacetal; this sulfide shows exceptionally high levels of enantioselectivity.