SYNTHESIS OF THE FIRST AMINE-DICARBOXYBORANES AND THEIR DERIVATIVES

Authors
BERENTE Z GYORI B
Citation
Z. Berente et B. Gyori, SYNTHESIS OF THE FIRST AMINE-DICARBOXYBORANES AND THEIR DERIVATIVES, Chemical communications, (18), 1997, pp. 1799-1800
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1997
Pages
1799 - 1800
Database
ISI
SICI code
1359-7345(1997):18<1799:SOTFAA>2.0.ZU;2-7
Abstract
The first amine-dicarboxyboranes and their dimethyl esters are synthes ized from amine-dicyanoboranes via [amine-bis(ethylnitrilium)hydroboro n(2+)] tetrafluoroborates, amine-bis(C-hydroxy-N-ethyliminium)hydrobor on(2+)] cations and amine-bis(N-ethylcarbamoyl)boranes; C-methoxy-N-et hyliminium groups adjacent to boron undergo unusual hydrolysis.