The experimental dependence of the apparent constant of formation of p
olychromium particles (K-3p) on PH was determined by the static ion ch
romatography method. The equilibrium forms of Cr(VI) particles were es
timated in solutions of acids. The effect of the presence of substitut
ed chromates on distribution of equilibrium forms of chromic acid was
evaluated. The change of acidic properties of Cr(VI) solutions was cal
culated with introduction of anions of various acids into their compos
ition.