INCORPORATION AND STABILITY OF CARBON DURING LOW-TEMPERATURE EPITAXIAL-GROWTH OF GE1-XCX (X-LESS-THAN-0.1) ALLOYS ON SI(100) - MICROSTRUCTURAL AND RAMAN STUDIES
Bk. Yang et al., INCORPORATION AND STABILITY OF CARBON DURING LOW-TEMPERATURE EPITAXIAL-GROWTH OF GE1-XCX (X-LESS-THAN-0.1) ALLOYS ON SI(100) - MICROSTRUCTURAL AND RAMAN STUDIES, Journal of applied physics, 82(7), 1997, pp. 3287-3296
Low-temperature (-200 degrees C) molecular beam epitaxy of Ge1-xCx all
oys grown on Si(100) have been extensively investigated by in situ ref
lection high-energy electron diffraction, ex situ x-ray diffraction, t
ransmission electron microscopy, and Raman spectroscopy. Carbon concen
trations were nominally varied from 0 up to similar to 10 at. %. Selec
ted samples were annealed in an Ar ambient at 750 degrees C to evaluat
e the stability of the thin films. A few films were also grown on Ge s
ubstrates. With increasing C concentration, the epitaxial growth mode
changes from two dimensional layer growth to three dimensional island
growth. The surface has a tendency to facet along {311} planes under c
ertain growth conditions, The microstructure shows an increase in plan
ar defect density with increasing C concentration. The x-ray diffracti
on data show that the lattice parameter decreases with increasing C co
ncentration and that a maximum of 1 at. % C is incorporated substituti
onally in Ge, Raman spectroscopy shows no clear Ge-C signal though ext
ra intensity is measured at the energies where Ge-C modes may be expec
ted. Films with nominal C concentrations greater than 2 to 3 at. % sho
w clear evidence for amorphous C. We propose that under our growth con
ditions, nominal C in excess of about 2 to 3 at. % remains on the surf
ace as amorphous C and plays an important role in 3D islanding, defect
formation, and {311} faceting during epitaxial growth. (C) 1997 Ameri
can Institute of Physics.