OXYHALOGENATION OF AROMATICS OVER COPPER PHTHALOCYANINES ENCAPSULATEDIN ZEOLITES

The oxychlorination and oxybromination, under near-ambient conditions, of benzene, toluene, phenol, aniline, anisole, and resorcinol, using as catalysts the phthalocyanines of Cu, Fe, and Co encapsulated in zeo lites X, Y, and L, are reported. Both H2O2 and O-2 have been used as o xidants. HCl and alkali chlorides/bromides have been used as sources o f halogens. The metal phthalocyanines wherein the aromatic rings are s ubstituted by -Cl or -NO2 groups are more active. There is a dramatic increase in the turnover frequencies for substrate conversion when the complexes are encapsulated in the cavities of the zeolites X, Y, or L . The oxyhalogenation of both the aromatic nucleus and the alkyl side chains occur. Oxidation of the aromatic ring (to phenols or cresols, f or example) does not occur. Alkyl side chains, however, are oxidized b y the oxidant H2O2 or O-2 to alcohols, ketones, and acids. The perform ance of these novel catalyst systems as solid oxyhalogenation catalyst s in utilizing O-2 and halide ions in the manufacture of halogenated a romatics holds promise in the organic chemicals industry. (C) 1997 Aca demic Press.