Al. Rogach et al., THE FORMATION OF HIGHLY DISPERSED SILVER BY THE REDUCTION OF AG-SOLUTIONS( IONS IN AQUEOUS), Colloid journal of the Russian Academy of Sciences, 56(2), 1994, pp. 221-223
A highly dispersed aqueous colloid of metallic silver was obtained by
reducing AgNO3 with NaBH4. Stabilization of the silver sol was achieve
d by adding sodium trimetaphosphate, polyvinyl alcohol, or some nitrog
en- and sulfur-containing surfactants. Small silver clusters were obta
ined by forming colloidal silver particles on a PVA-based polymer matr
ix, which impeded oxidation and coagulation of silver particles at ear
ly stages of reduction.