Rb. Grayson et al., CATCHMENT-WIDE IMPACTS ON WATER-QUALITY - THE USE OF SNAPSHOT SAMPLING DURING STABLE FLOW, Journal of hydrology, 199(1-2), 1997, pp. 121-134
Water quality is usually monitored on a regular basis at only a small
number of locations in a catchment, generally focused at the catchment
outlet. This integrates the effect of all the point and non-point sou
rce processes occurring throughout the catchment. However, effective c
atchment management requires data which identify major sources and pro
cesses. As part of a wider study aimed at providing technical informat
ion for the development of integrated catchment management plans for a
5000 km(2) catchment in south eastern Australia, a 'snapshot' of wate
r quality was undertaken during stable summer flow conditions. These l
ow flow conditions exist for long periods so water quality at these fl
ow levels is an important constraint on the health of in-stream biolog
ical communities. Over a 4 day period, a study of the low flow water q
uality characteristics throughout the Latrobe River catchment was unde
rtaken. Sixty-four sites were chosen to enable a longitudinal profile
of water quality to be established. All tributary junctions and sites
along major tributaries, as well as all major industrial inputs were i
ncluded. Samples were analysed for a range of parameters including tot
al suspended solids concentration, pH, dissolved oxygen, electrical co
nductivity, turbidity, Bow rate and water temperature. Filtered and un
filtered samples were taken from 27 sites along the main stream and tr
ibutary confluences for analysis of total N, NH4, oxidised N, total P
and dissolved reactive P concentrations. The data are used to illustra
te the utility of this sampling methodology for establishing specific
sources and estimating non-point source loads of phosphorous, total su
spended solids and total dissolved solids. The methodology enabled sev
eral new insights into system behaviour including quantification of un
known point discharges, identification of key in-stream sources of sus
pended material and the extent to which biological activity (phytoplan
kton growth) affects water quality. The costs and benefits of the samp
ling exercise are reviewed.