PREPARATION OF N,N-DIALKYL-N'-PERFLUOROALKANESULFONYLFORMAMIDINES RFSO2,N=CHNR2 VIA VILSMEIER REAGENTS

Authors
XU GL XU B QIN CY ZHU SZ
Citation
Gl. Xu et al., PREPARATION OF N,N-DIALKYL-N'-PERFLUOROALKANESULFONYLFORMAMIDINES RFSO2,N=CHNR2 VIA VILSMEIER REAGENTS, Journal of fluorine chemistry, 84(1), 1997, pp. 25-28
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
84
Issue
1
Year of publication
1997
Pages
25 - 28
Database
ISI
SICI code
0022-1139(1997)84:1<25:PONR>2.0.ZU;2-#
Abstract
Treatment of sodium perfluoroalkanesulfonylamides RfSO2NHNa with Vilsm eier reagents [YCH=+NR2]Cl-(Y=OP(O)Cl-2,OS(O)Cl) give the title compou nds RfSO2N=CHNR2 in good yields. The molecular structure of I(CF2)(2)O (CF2)(2)SO2N=CHNMe2 is presented. (C) 1997 Elsevier Science S.A.