A TRIFLUOROMETHYL GROUP DIRECTED SEMIPINACOL REARRANGEMENT - SYNTHESIS OF ALPHA-(TRIFLUOROACETYL) DIARYLMETHANES

Authors
HORNYAK G FETTER J NEMETH G POSZAVACZ L SIMIG G
Citation
G. Hornyak et al., A TRIFLUOROMETHYL GROUP DIRECTED SEMIPINACOL REARRANGEMENT - SYNTHESIS OF ALPHA-(TRIFLUOROACETYL) DIARYLMETHANES, Journal of fluorine chemistry, 84(1), 1997, pp. 49-51
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
84
Issue
1
Year of publication
1997
Pages
49 - 51
Database
ISI
SICI code
0022-1139(1997)84:1<49:ATGDSR>2.0.ZU;2-3
Abstract
Semipinacol rearrangements of trifluoromethyl substituted vic-diol mon omethyl ethers proceeded smoothly to give alpha-(trifluoroacetyl) diar ylmethanes in good yields, The trifluoromethyl group gave specific ori entation to the course of the rearrangement. (C) 1997 Elsevier Science S.A.