SYNTHESIS AND CHARACTERIZATION OF NEW PENTAFLUOROPHENYLBISMUTH(V) DERIVATIVES

Authors
NAUMANN D TYRRA W LEWE T
Citation
D. Naumann et al., SYNTHESIS AND CHARACTERIZATION OF NEW PENTAFLUOROPHENYLBISMUTH(V) DERIVATIVES, Journal of fluorine chemistry, 84(1), 1997, pp. 69-73
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
84
Issue
1
Year of publication
1997
Pages
69 - 73
Database
ISI
SICI code
0022-1139(1997)84:1<69:SACONP>2.0.ZU;2-I
Abstract
The reactions of tris (pentafluorophenyl) bismuth difluoride with chlo rotrimethylsilane, trimethylsilicontrifluoroacetate and trimethylsilic ontrifluoromethanesulphonate gives tris(pentafluorophenyl) bismuth dic hloride, bis(trifluoroacetate) and bis(trifluoromethanesulphonate) in nearly quantitative yields. The products were identified by F-19 and C -13{F-19} NMR spectroscopy. The products of the thermal decomposition are described. (C) 1997 Elsevier Science S.A.