A. Ohsaki et al., PORTULENE ACETAL, A NOVEL MINOR CONSTITUENT OF PORTULACA-GRANDIFLORA WITH SIGNIFICANCE FOR THE BIOSYNTHESIS OF PORTULAL, Journal of natural products, 60(9), 1997, pp. 912-914
A new clerodane diterpenoid (6) with a caged hemiacetal ring has been
isolated as a minor constituent from Portulaca grandiflora and its str
ucture elucidated by extensive spectral studies. The compound might be
of significance in the biosynthesis and in the chemosystematics of co
nstituents of the genus Portulaca. The structural features of 6 provid
e important clues for the proposal of a chemically reasonable scheme f
or the biosynthesis of portulal (1).