X-RAY CRYSTAL-STRUCTURE OF DISAZO DYES .1. CI-DISPERSE-ORANGE-29

Authors
FREEMAN HS MCINTOSH SA SINGH P
Citation
Hs. Freeman et al., X-RAY CRYSTAL-STRUCTURE OF DISAZO DYES .1. CI-DISPERSE-ORANGE-29, Dyes and pigments, 35(1), 1997, pp. 11-21
Citations number
9
Categorie Soggetti
Chemistry Applied
Journal title
Dyes and pigments → ACNP
ISSN journal
01437208
Volume
35
Issue
1
Year of publication
1997
Pages
11 - 21
Database
ISI
SICI code
0143-7208(1997)35:1<11:XCODD.>2.0.ZU;2-J
Abstract
Crystals of C.I. Disperse Orange 29, a disazo dye, were grown from a m ethanol solution and the X-ray structure was solved from 2484 independ ent reflections to R = 0.0497. Results showed that the crystal examine d exists in the triclinic space group PI. Interestingly, the structure generated possessed a syn conformation, unlike 4-phenylazoazobenzene which is known to exist in the anti conformation. (C) 1997 Elsevier Sc ience Ltd.