SHORT SYNTHESIS OF CHIRAL TENTACLED PORPHYRINS USING PYRROLYLMAGNESIUMBROMIDE AND (3R)-(-CITRONELLAL())

Authors
CORNIA M CAPACCHI S PORCARI S TARASCONI P
Citation
M. Cornia et al., SHORT SYNTHESIS OF CHIRAL TENTACLED PORPHYRINS USING PYRROLYLMAGNESIUMBROMIDE AND (3R)-(-CITRONELLAL()), Tetrahedron : asymmetry, 8(17), 1997, pp. 2885-2887
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
8
Issue
17
Year of publication
1997
Pages
2885 - 2887
Database
ISI
SICI code
0957-4166(1997)8:17<2885:SSOCTP>2.0.ZU;2-F
Abstract
The reaction between pyrrolyrmagnesiumbromide and (3R)-(+)-citronellal produced porphyrin 1 with four chains at the meso carbons, each one b earing a stereogenic centre at C-2 and a double bond at C-5. '-Fluoro- phenyldipyrryl-methanebismagnesiumbromide 4 with (3R)-(+)-citronellal gave rise to porphyrin 2 with two stereogenic chains. (C) 1997 Publish ed by Elsevier Science Ltd.