LITHIUM N-LITHIOMETHYLDITHIOCARBAMATES - NEW N-ALKYLAMINOMETHYL ANIONEQUIVALENTS .3. 2-IMIDAZOLIDINETHIONES AND 1,2-DIAMINES VIA ELECTROPHILIC AMINOALKYLATION WITH IMINES AND IMINIUM SALTS
H. Ahlbrecht et C. Schmitt, LITHIUM N-LITHIOMETHYLDITHIOCARBAMATES - NEW N-ALKYLAMINOMETHYL ANIONEQUIVALENTS .3. 2-IMIDAZOLIDINETHIONES AND 1,2-DIAMINES VIA ELECTROPHILIC AMINOALKYLATION WITH IMINES AND IMINIUM SALTS, Synthesis, (7), 1994, pp. 719-722
Treatment of lithium N-butyl-N-lithiomethyldithiocarbamates 3 with var
ious aldimines and ketimines 4 leads to 1,3,4,4-tetrasubstituted 2-imi
dazolidinethiones 6. If iminium salts 7 are used as electrophiles, uns
ymmetrically substituted 1,2-diamines 8 are obtained.