PHENOL-FORMALDEHYDE BASED WEAK-BASE RESINS FOR THE RECOVERY OF GOLD

Authors
Citation
I. Tyc et Br. Green, PHENOL-FORMALDEHYDE BASED WEAK-BASE RESINS FOR THE RECOVERY OF GOLD, Solvent extraction and ion exchange, 12(4), 1994, pp. 817-830
Citations number
14
Categorie Soggetti
Chemistry
ISSN journal
07366299
Volume
12
Issue
4
Year of publication
1994
Pages
817 - 830
Database
ISI
SICI code
0736-6299(1994)12:4<817:PBWRFT>2.0.ZU;2-P
Abstract
In a process for the recovery of gold-cyanide with a weak-base resin, it is desirable that the resin should load gold at the natural pH of t he leach liquor and be stripped by an aqueous alkali. The present work explores, for such a resin, the potential of a phenol-formaldehyde po lymer matrix which, it was thought, would facilitate the stripping of gold. Unexpected loading behaviour of a resin with an imidazoline acti ve group is rationalized from results obtained during its titration. I t is concluded that a phenol-formaldehyde matrix might limit the upper pH at which a resin can load, and its effect on pH functionality will depend on the concentration of phenolic groups. Magnetic separation i s a possible technique for separating a resin from a pulp. The method of synthesis of phenol-formaldehyde polymers can be adapted to prepare composite resins containing magnetic materials.