At zero pressure polymerized RbC60 is an insulator, whereas polymerize
d KC60 is a metal with a slight low-temperature resistive upturn. We r
eport measurements of the resistivity of RbC60 under pressure, finding
a hysteretic resistive transition in RbC60 near 200 K at 5 kbar, at w
hich point the material transforms from insulator to metal. Correcting
the resistivity to constant volume, both materials are metallic below
the transition with a common low-temperature resistive upturn which i
s suppressed under compression.