METAL-INSULATOR-TRANSITION IN A C-60 - RBC60 AND KC60

Citation
K. Khazeni et al., METAL-INSULATOR-TRANSITION IN A C-60 - RBC60 AND KC60, Physical review. B, Condensed matter, 56(11), 1997, pp. 6627-6630
Citations number
28
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
01631829
Volume
56
Issue
11
Year of publication
1997
Pages
6627 - 6630
Database
ISI
SICI code
0163-1829(1997)56:11<6627:MIAC-R>2.0.ZU;2-U
Abstract
At zero pressure polymerized RbC60 is an insulator, whereas polymerize d KC60 is a metal with a slight low-temperature resistive upturn. We r eport measurements of the resistivity of RbC60 under pressure, finding a hysteretic resistive transition in RbC60 near 200 K at 5 kbar, at w hich point the material transforms from insulator to metal. Correcting the resistivity to constant volume, both materials are metallic below the transition with a common low-temperature resistive upturn which i s suppressed under compression.